Hybrid Lithium-Ion / Lithium-Metal Battery Electrolyte for Fast Charging and High Energy Density

Executive Summary

Lithium ion batteries are currently ubiquitous in numerous applications while lithium metal batteries are becoming closer to commercialization. For all batteries, there is a continuous need for higher energy density and fast charging and discharging due to growing applications such as e-vehicles. One limitation of lithium based batteries is the problem of lithium dendrite formation during fast charging which can cause shorts and fires. Researchers at Michigan State University have recently developed a new electrolyte system for lithium batteries that allows fast charging without dendrite formation. The electrolyte allows lower than 1 N/P ratios of anode/cathode capacity and thus high energy densities above 300 W/kg.

 

Description of the Technology

The technology for Li-ion and Li-metal battery systems uses a new electrolyte system. The electrolyte system has been tested on 2032 coin cell configuration test apparatus with a graphite anode and LiNMC811 cathode. Comparisons have been made to “Gen 2” LiPF6 EC:EMC electrolytes. After 2000 cycles at fast charging, the system had neglible areal discharge capacity and maintained 90% columbic efficiency.

 

Benefits

  • Low N/P levels down to 0.7
  • High energy densities over 300 W/kg
  • Allows fast charging (< 15 min) of batteries and low temperature (-30oC) operation
  • Superior cycle performance (tested over 2000 cycles) at fast charging rates compared to leading benchmark
  • Can be used in existing battery configurations

 

Applications

  • Li-ion batteries
  • Li-metal batteries

 

Patent Status

Patent pending, published application

 

Licensing Rights

Full licensing rights available

 

Inventors

Dr. Chengcheng Fang, Robert Kuphal

 

TECH ID

TEC2023-0082

Patent Information:

Category(s):

For Information, Contact:

Jon Debling
Technology Manager
Michigan State University
deblingj@msu.edu
Keywords:
Lithium Batteries